Hi all,
Like Bob and Lornek say pH is a movable feast at low levels of buffering. Even the CO2 dissolved from the atmosphere will cause the pH to crash.
Have a look at the buffering section of this reply:
http://www.plecoplanet.com/forum/showthread.php?t=4506.
Again as Bob says conductivity or TDS (divide conductivity (in microS) by 0.62 to give TDS ppm), is a more useful measure, but doesn't tell you what salts you have. It is usually suggested re-mineralizing to 4 dKH with re-mineralising salts (you can make your own with magnesium/calcium sulphate/carbonate/chloride).
I've found a couple of useful diagrams for the processes in:
Hard water:
Soft water
As an example rainwater from the water butt at home (Wiltshire) is about 150 microS in the summer, 80microS in the winter. Water out of the de-ioniser in the lab. is about 3 microS, and about 20microS out of the steam distillation unit.
My tap water is about 620 microS, and a fairly stable pH of 7.8 - 8.0 (it has about 17d carbonate hardness so is strongly carbonate buffered. Figures from Wessex water)
Calcium (milligrams per litre) 119 (298 x 40% = 119)
Calcium carbonate (milligrams per litre) 298
Degrees German (ºdH) 16.7 (16.7 x 17.85 = 298)
Degrees French (ºf) 30
Degrees Clark 21
Sodium (milligrams per litre) 22
Conductivity 615 micro S(iemens)
cheers Darrel