Ammonia, Nitrite and PH

Doodles

Retired Staff
Apr 8, 2009
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PH(and the temp) play a part in how toxic ammonia is. The lower the PH(and temp) the less toxic ammonia is. A few weeks ago I was reading about nitrite and PH, where it said lower PH meant that nitrite would be more toxic(can't remember where i read it). Just wondering if its true?
 

Lornek8

Member
Apr 21, 2009
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Hawaii
Just did a quick google search & it seems to be true. It goes along with why ammonia toxicity varies with pH. There are two forms of nitrite, NO2 & HN02. HNO2 is more toxic & the precentage of it in the total nitrite increases as pH decresases.
 

dw1305

Global Moderators
Staff member
May 5, 2009
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Wiltshire nr. Bath, UK
Hi all,
HNO2 is "nitrous acid". I think the reason for greater toxicity at low pH is that nitrous acid does not need to actively transported across the gills (nitrite does), and once in the fishes alkaline blood it will lose the H+ and become NO2, so basically the fish gets a bigger dose of NO2 in acidic water.

I think this is the same reason why chlorides protect against NO2 poisoning, a high level of Cl- ions means that less NO2- ions are transported across the gill membranes. Apparently CaCl2 is more efficient at reducing NO2 poisoning than NaCl.

Details here: <http://www.global-scientific-inc.com/tcru/kc/pubs/parker/p58nitrite/58nitrite.htm> It is well worth a read.

cheers Darrel