tank is 125l and does have 4 plants in. I did check the media and it was all in good shape. I thought about food, the only different thing I have fed is Max's earthworm pellets!! Good idea about the second filter, now I have moved over to externals I have plenty of spare internals.strange, never seen that before.
could some of the filter media be breaking down? may be worth partially replacing some? at least take it out and see if it will cruble or something?
are you using different food? could it be some food waste?
you dont mention any plants? how big is the tank?
for tanks with precious zebs in I run a small internal filter as well for back up - usually the ones with built in UV (aquael) for extra safty against infection.